Bretherton , C. S. , MacVean , M. K. , Bechtold , P. , Chlond , A. , Cotton , W. R. , Cuxart , J. , Cuijpers , H. , Khairoutdinov , M. , Kosovic , B. , Lewellen , D. , Moeng , C. H. , Sibiesma , P. , Stevens , B. , Stevens , D. E. , Sykes , I. and Wyant , M. C . 1999 . An intercomparison of radiatively driven entrain-ment and turbulence in a smoke cloud, as simulated by different numerical models . Q. J. R. Meteorol. Soc ., 125 , 391 – 423 .
Cuijpers , J. W. M. and Duynkerke , P. G . 1993 . Large eddy simulations of trade wind with cumulus clouds. J. Atmos. Sc i . 50 , 3894 – 3908 .
Cuijpers , J. W. M. and Holtslag , A. A. M . 1998 . Impact of skewness and nonlocal effects on scalar and buoyancy fluxes in convective boundary layers. J. Atmos. Sc i . 55 , 151 – 162 .
Deardorff , J. W . 1974 . Three-dimensional numerical study of turbulence in an entraining mixed layer . Boundary Layer MeteoroL 7 , 199 – 226 .
Deardorff , J. W . 1979 . Prediction of convective mixed-layer entrainment for realistic capping inversion structure. J. At-mos. Sc i . 36 , 424 – 436 .
Gao , W. and Wesely , M. L . 1994 . Numerical modelling of the turbulent fluxes of chemically reactive trace gases in the atmospheric boundary layer . J. AppL MeteoroL 33 , 835 – 847 .
Hamba , E 1993 . A modified K model for chemically reactive species in the planetary boundary layer . J. Geophys. Res . 98 , 5173 – 5182 .
Herwehe , J. A. , McNider , R. T. and Newchurch , M. J . 2000. A numerical study of the effects of large eddies on pho-tochemistry in the convective boundary layer. 14th Sym-posium on Boundary Layers and Turbulence. American Meteorological Society, 235 – 238
Krol , M. C. , Molemaker , M. J. and Vilà-Guerau de Arel-lano , J. 2000 . Effects of turbulence and heterogeneous emissions on photochemically active species in the cconvective boundary layer . J. Geophys. Res . 105 , 6871 – 6884 .
Lenschow , D. H. , Wyngaard , J. C and Pennell, W. T. 1980. Mean-field and second-moment budgets in a baroclinic, convective boundary layer. J. Atmos. Sci . 37 , 1313 – 1326.
McDonald-Butler , E. C. , Liljestrand , H. M. and Sepehrnoori , K . 1999 . Numerical modeling of dry deposition coupled to 22 photochemical reactions . Atmos. Environ . 33 , 1491 – 1502 .
Moeng , C. H. and Wyngaard , J. C. 1984. Statistics of conser-vative scalars in the convective boundary layer. J. Atmos. Sci . 41 , 3161 – 3169.
Moeng , C.-H. and Wyngaard , J. C. 1989. Evaluation of tur-bulent transport and dissipation closures in second-order modeling. J. Atmos. Sci . 46 , 2311 – 2330.
Molemaker , M. J. and Vilà-Guerau de Arellano, J. 1998. Turbulent control of chemical reactions in the convective boundary layer. J. Atmos. Sci . 55 , 568 – 579.
Patton , E. G. , Davis , K. J. , Barth , M. C. and Sullivan , P. P. 2001. Decaying scalars emitted by a forest canopy: a nu-merical study. Boundary Layer MeteoroL 100, 91 – 129.
Petersen , A. C. and Holtslag , A. A. M . 1999 . A first-order closure for covariances and fluxes of reactive species in the convective boundary layer . J. Appl. MeteoroL 38 , 1758 – 1776 .
Petersen , A. C. , Beets , C. , van Dop , H. and Duynkerke , P. G . 1999 . Mass-flux schemes for transport of non-reactive and reactive scalars in the convective boundary layer . J. Atmos. Sci . 56 , 37 – 56 .
Petersen , A. C . 2000 . The impact of chemistry on flux esti-mates in the convective boundary layer . J. Atmos. Sci . 57 , 3398 – 3405 .
Poppe , D. and Lustfeld , H . 1996 . Nonlinearities in the gas phase chemistry of the troposphere: Oscillating concen-trations in a simplified mechanism . J. Geophys. Res . 101 , 14373 – 14380 .
Schumann , U . 1989 . Large-eddy simulation of turbulent dif-fusion with chemical reactions in the convective boundary layer . Atmos. Environ . 23 , 1713 – 1729 .
Siebesma , A. P. and Cuijpers , J. W. M. 1995. Evaluation of parametric assumptions for shallow cumulus convection. J. Atmos. Sci . 52 , 650 – 666.
Stockwell , R. W. , Middleton , R , Chang, J. S. and Tang, X. 1990. The second generation regional acid deposition model chemical mechanism for regional air quality mod-eling. J. Geophys. Res . 96 , 16343 – 16367.
Sykes , R. I. , Parker , S. F. , Henn , D. S. and Lewellen , W. S. 1994. Turbulent mixing with chemical reactions in the planetary boundary layer. J. AppL MeteoroL 33 , 825 – 834.
Verver , G. H. L. 1994. Comment on “a modified K model for chemically reactive species in the planetary boundary layer” by Fujihiro Hamba. J. Geophys. Res . 99 , 19021 – 19023.
Verver , G. H. L. , van Dop , H. and Holtslag , A. A. M . 1997 . Turbulent mixing of reactive gases in the convec-tive boundary layer . Boundary Layer Meteorol . 85 , 197 – 222 .
Vilà-Guerau de Arellano , J. and Cuijpers , J. W. M. 2000. The chemistry of a dry cloud: the effects of radiation and turbulence. J. Atmos. Sci . 57 , 1573 – 1584.
Vilà-Guerau de Arellano , J. and Lelieveld , J. 1998. Chemistry in the atmospheric boundary layer. In: Clear and cloudy boundary layers (eds. A. A. M. Holtslag and P. G. Duynkerke ). Royal Netherlands Academy of Arts and Sciences , Amsterdam, The Netherlands , 267 – 286
Vilà-Guerau de Arellano , J. , Duynkerke , P. G. , Jonker , P. J. and Builtjes , P. J. H. 1993. An observational study on the effects of time and space averaging in photochemical models. Atmos. Environ. 27 , 353 – 362.
Wyngaard , J. C . 1983. Lectures on the planetary boundary layer. In: Mesoscale meteorology-Theories, observations and models. NATO ASI Series, D. Reidel, Dordrecht, 603 – 650
Wyngaard , J. C . 1985 . Structure of the planetary boundary layer and implications for its modeling . J. Climate AppL MeteoroL 24 , 1131 – 1142 .
Wyngaard , J. C. and Brost , R. A . 1984 . Top-down and bottom-up diffusion of a scalar in the convective boundary layer . J. Atmos. Sci . 41 , 102 – 112 .
Wyngaard , J. C. , Pennell , W. T. , Lenschow , D. H. and LeMone , M. A . 1978 . The temperature-humidity covari-ance budget in the convective boundary layer . J. Atmos. Sci . 35 , 47 – 58 .