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    Original Research Papers

    Enhancement of snowpack inorganic nitrogen by aerosol debris

    Authors:

    J . L. Wadham ,

    Bristol Glaciology Centre, School of Geographical Sciences, GB
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    K. R. Hallam,

    University of Bristol, Interface Analysis Centre, GB
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    J. Hawkins,

    University of Bristol, Interface Analysis Centre, GB
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    A. O’connor

    Bristol Glaciology Centre, School of Geographical Sciences, GB
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    Abstract

    The NO3 -, Cl- and Ca2 + loading and provenance of the lower wetted-refrozen part of an Arctic snowpack sampled in spring 1999 is analysed. This wetted-refrozen layer (WRL) formed during rain-on-snow events in early winter 1998, being subsequently buried by later snowfall. It is a unique environment within which to study NO3 - provenance, since it is effectively sealed off from the atmosphere, and solute is mostly stored in superimposed ice, ice lenses and wetted-refrozen snow. Post-depositional losses/gains of NO3 - by volatilization/dry deposition are, therefore, minimized. Partitioning of WRL Ca2+ and NO3 - loads into their respective sea salt/atmospheric components and an excess component indicates significant contributions of excess Ca2+ (∼80% of total) and NO3 - (11–64% of total). These excess loads are thought to arise from a combination of preferential elution during lateral meltwater drainage and the release of Ca+ and N (as NO3 - and NH4 +) from snowpack debris during wetting. Dissolution experiments on local snowpack debris provide envelopes of Ca2+ and NO3 - release that are in line with the excess loads of these species at most sampling sites and are supportive of the latter hypothesis. This is the first study to date to indicate debris as a possible source of non-atmospheric nitrogen to snow. It has implications for nitrogen cycling in other catchments where snow contains significant aerosol sourced from N-containing lithologies and organic matter

    How to Cite: Wadham, J.L., Hallam, K.R., Hawkins, J. and O’connor, A., 2006. Enhancement of snowpack inorganic nitrogen by aerosol debris. Tellus B: Chemical and Physical Meteorology, 58(3), pp.229–241. DOI: http://doi.org/10.1111/j.1600-0889.2006.00180.x
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      Published on 01 Jan 2006
    Peer Reviewed
     CC BY 4.0
     Accepted on 15 Nov 2005            Submitted on 17 Aug 2004

    References

    1. Bales , R. C. , Davies , R. E. and Stanley , D. A . 1989 . Ion elution through shallow homogenous snow . Water Resour. Res . 25 , 1869 – 1877 .  

    2. Baron , J. L. , Allston , E. J. and Newkirk , B. K . 1995 . Analysis of long term sulphate and nitrate budgets in a Rocky Mountain basin . Biogeo-chemistry of Seasonally Snow-covered Catchments, IAHS Publication No . 228 , 255 – 261  

    3. Beer , J. , Finkel , R. C. , Bonani , H. , Görlach , U. , Jacob , P. and co-authors 1991. 2003. Seasonal variations in the concentration of 10Be, Cl—, NO3, 5042, NO3, H202, 210pb, 3H, mineral dust and 3180 in Greenland snow. Atmos. Environ. 25A(5-6), 899 – 904.  

    4. Beine , H. J. , Domine , E , Ianniello , A. , Nardino , M. , Allegrini , I. and co-authors 2003. Fluxes of nitrates between snow surfaces and the atmosphere in the European high Arctic. Atmos. Chem. Phys. 3, 335 – 346  

    5. Bieber , A. J. , Williams , M. A. , Johnsson , M. J. and Davinroy , T. C . 1998 . Nitrogen Transformations in Alpine Talus Fields, Green Lakes Valley, Front Range, Colorado, U.S.A . Arctic Alpine Res . 30 , 266 – 271 .  

    6. Brimblecombe , P. , Tranter , M. , Abrahams , P. W. , Davies , T. D. and Vm-cent , C. E . 1985 . Relocation and preferential elution of acidic solute through the snowpack of a small, remote, high altitude Scottish catch-ment . Ann. Glaciol . 7 , 141 – 147 .  

    7. Brooks , P. , Schmidt , S. , Sommerfeld , R. and Musselman , R. 1993. Dis-tribution and abundance of microbial biomass in Rocky Mountain Spring Snowpacks. Proc. Eastern Snow Conf. 50, 301 – 306.  

    8. Brown , G. H. , Tranter , M. and Sharp , M. J . 1996 . Experimental inves-tigations of the weathering of suspended sediment by alpine glacial meltwater . Hydrological Processes 10 , 579 – 597 .  

    9. Cadle , S. H. , Dasch , J. M. and Mulawa , P. A . 1985. Atmospheric con-centrations and the deposition velocity to snow of nitric acid, sulphur dioxide and various particulate species . Atmos. Environ . 19 , 1819– 1985 .  

    10. Campbell , D. H. , Ban-on , J. L. , Tonessen , K. A. , Brooks , P. D. and Schster , P. E 2000. Controls on nitrogen flux in alpine/subalpine wa-tersheds of Colorado. Water Resour. Res. 36 , 37 – 47.  

    11. Dasch , D. M. and Cadle , S. H . 1986 . Dry deposition to snow in an urban area . Water Air Soil Pollut . 29 , 297 – 308 .  

    12. Davies , T. D. , Vmcent , C. E. and Brimblecombe , P . 1984 . Preferential elution from a Norwegian ice cap . Nature 300 , 161 – 163 .  

    13. Davies , T. D. , Brimblecombe , P. , Tranter , M. , Tsiouris , S. , Vmcent , C. E. and co-authors 1987. The removal of soluble ions from melting snowpacks. In: Seasonal Snowcovers: Physics, Chemistry, Hydrology, Les Arcs, July 1986 (eds H. G. Jones and W. J. 0. Thomas). NATO Advanced Study Institute Series C, D. Reidel, Derdrecht, Vol. 211, 337 – 392.  

    14. Delmas , V. , Jones , H. G. , Tranter , M. and Delmas , R . 1996 . The weath-ering of aeolian dusts in alpine snows ., Atmos. Environ . 30 ( 8 ), 1317 – 1325 .  

    15. Dubowski , Y. , Colussi , A. J. and Hoffmann , M. R . 2001 . Nitrogen dioxide release in the 302 nm band of photolysis of spray frozen aqueous nitrate solutions: Atmospheric Implications. ./ . Phys. Chem. A 105 , 4928 – 4932 .  

    16. Eichler , A. , Schwikowaki , M. and Gggeler , H. W . 2001 . Meltwater in-duced relocation of chemical species in Alpine fim . Tellus 53B , 192 – 203 .  

    17. Fischer , H. , Wagenbach , D. and Kipfstuhl , J . 1998. Sulfate and nitrate fim concentrations on the Greenland Icesheet 2. Temporal anthropogenic deposition changes. J. Geophys. Res. Lett. 103(D17), 21,935 – 21,942.  

    18. Guildford , S. J. and Hecky , R. E . 2000 . Total nitrogen, total phospho-rus, and nutrient limitation in lakes and oceans: Is there a common relationship? Limnol. Oceanogr . 45 , 1213 – 1223 .  

    19. Hendry , M. J. , McCready , G. L. and Gould , W. D . 1984 . Distribution, source and evolution of a nitrate in a glacial till in southern Alberta, Canada . J. Hydrol . 70 , 177 – 198 .  

    20. Hinkley , T. K . 1994 . Composition and sources of atmospheric dusts in snow at 3200 meters in the St Elias range, Southeastern Alaska, USA . Geochimica et Cosmochimica Acta . 58 , 3245 – 3254 .  

    21. Hodson , A. J. , Mumford , P. N. , Kohler , J. and Wynn , P . 2005 . The High Arctic glacial ecosystem: new insights from nutrient budgets . Biogeo-chemistry 72 , 233 – 256 .  

    22. Holland , E. A. , Dentener , E J. , Braswell , B. H. and Sulzman , J. M . 1999 . Contemporary and pre-industrial global reactive nitrogen bud-gets . Biogeochemistry 46 , 7 – 43 .  

    23. Holland , H. D . 1978 . The Chemistry of the Atmosphere and the Oceans . Wiley-Interscience , New York .  

    24. Holland , E. A. , Dentener , E J. , Braswell , B. H. and Sulzman , J. M . 1999 . Contemporary and pre-industrial global reactive nitrogen bud-gets . Biogeochemistry 46 , 7 – 43 .  

    25. Holloway , J. M. and Dahlgren , R. A . 2001 . Seasonal and event-scale variations in solute chemistry for four Sierra Nevada catchments . J. Hydrol . 250 , 106 – 121 .  

    26. Holloway , J. M. and Dahlgren , R. A . 2002 . Nitrogen in rock: occurrences and biogeochemical implications . Global Biogeochemical Cycles 16 , 1118 .  

    27. Hogan , A. W. , Barnard , S. , Wolfe , D. , Dubois , M. and Pitaniello , A. M . 1985 . Chemical migration in a mid-latitude snow pack . Proc. Eastern Snow Conf . 42 , 243 – 254 .  

    28. Honrath , R. E. , Peterson , Guo S. , Dibb , J. E. , Shepson , P. B. and co-authors 1999. Evidence of NO3— production within or upon ice par-ticles in the Greenland snowpack. Geophys. Res. Lett. 26 , 695 – 698.  

    29. Johansson , C. and Granat , L . 1986 . An experimental study of the dry dep-osition of gaseous nitric acid to snow . Atmos. Environ . 20 , 1165 – 1170 .  

    30. Jones , A. E. , Weller , R. , Wolff , E. W. and Jacobi , H. W . 2000 . Speciation and rate of Photochemical NO and NO2 Production in Antarctic Snow . Geophys. Res. Lett . 27 , 345 – 348 .  

    31. Jones , A. E. , Weller , R. , Anderson , P. S. , Jacobi , H. W. , Wolff , E. W. and co-authors 2001. Measurement of NO emissions from the Antarctic snowpack. Geophys. Res. Lett. 28, 1499 – 1502.  

    32. Jones , H. G . 1991. Snow chemistry and biological activity: a particular perspective of nutrient cycling. In: Seasonal Snowpacks, Processes of Compositional Change (eds T. D. Davies, M. Tranter and H. G. Jones), NATO ASI series G: Ecol. Sci., 28, Springer Verglag, Berlin, 21 – 66.  

    33. Jones , H. G . 1999 . The ecology of snow-covered systems: a brief overview of nutrient cycling and life in the cold . Hydrolog. Proc . 13 , 2153 – 2147 .  

    34. Kekonen , T. , Moore , J. C. , Mulvaney , R. , Isaksson , E. , Pohjola , V. and co-authors 2002. A 800 year record of nitrate from the Lomonosovfonna ice core. Svalbard. Ann. Glaciol. 35, 261 – 265.  

    35. Kuhn , M . 2001 . The nutrient cycle through snow and ice, a review . Aquatic Sci . 63 , 150 – 167 .  

    36. Legrand , M. , Wolff , E. and Wagenbach , D . 1999 . Antarctic aerosol and snowfall chemistry: implications for deep Antarctic ice-core chem-istry . Ann. Glaciol . 29 , 66 – 72 .  

    37. Matoba , S. , Narita , H. , Motoyama , H. , Kamiyama , K. and Watanabe, 0. 2002. Ice core chemistry of Vestfonna Ice Cap in Svalbard, Norway. J. Geophys. Res.—Atmos . 107 (1)23) , 4721, 101029 .  

    38. Maupetit, E and Delmas, R. J . 1994 . Snow chemistry of high altitude glaciers in the French Alps . Tellus Series B-Chemical and Physical Meteorology 46 , 304 – 324 .  

    39. Mayewski , P. A. , Spencer , M. J. , Lyons , B. W. M. and Twickler , M. S. 1987. Seasonal and spatial trends in South Greenland snow chemistry. Atmos. Environ. 21, 863 – 869.  

    40. Mulvaney , R. , Wagenbach , D. and Wolff , E. W. 1998. Postdepositional change in snowpack nitrate from observation of year round near-surface snow in coastal Antarctica. J. Geophys. Res . 103(1)9), 11021 – 11031.  

    41. O'Connor , A . 2004. The temporal flux of nutrients from crustal dust aerosols located in a glacial environment:impliocations for snow ecosystems, masters thesis, University of Bristol, UK.  

    42. Pomeroy , J. W. , Davies , T. D. , Jones , H. G. , Marsh , P. , Peters , N. E and co-authors 1999. Transformations of snow chemistry in the Boreal forest: accumulation and volatilization. Hydrolog. Proc. 13, 2257 – 2273.  

    43. Rohrbough , J. A. Davies , D. R. and Bales , R. C . 2003 . Spatial variability of snow chemistry in an alpine snowpack, southern Wyoming . Water Resour. Res . 39 , 1190 .  

    44. Rahlisberger , R. , Hutterli , M. A. , Wolf , E. W. , Mulvaney , R. , Fischer , H. and co-authors 2002. Nitrate in Greenland and Antarctic ice cores: A detailed description of post-depositional processes. Ann. Glaciol. 35, 209 – 216.  

    45. Ruth , U. , Wagenbach , D. , Bigler , M. , Steffensen , J. P. , Rothlisberger , R. and co-authors 2002. High-resolution microparticle profiles at North-GRIP, Greenland: case studies of the calcium—dust relationship. Ann. Glaciol. 35, 237 – 242.  

    46. Sawstrom , C. , Mumford , P. , Marshall , W. , Hodson , A. and Layboum-Parry , J. 2002. The microbial communities and primary productivity of cyoconite holes in an Arctic glacier (Svalbard 79° N). Polar Biol. 25 , 591 – 596.  

    47. Schwikowski , M. , Seibert , P. , Baltensperger , U. and Gaggeler , H. W. 1995. A study of an outstanding saharan dust event at the high Alpine site Jungfraujoch, Switzerland . Atmos. Environ . 29 , 1829– 1842 .  

    48. Semb , A. , Brwkkan and Joranger, E. 1984. Major ions in Spitsbergen snow. Geophys. Res. Lett. 11, 445 – 448.  

    49. Shrestha , A. B. , Wake , C. P. , and Dibb , J. E. 1997. Chemical composition of aerosol and snow in the high Himalaya during the summer monsoon season. Atmos. Environ. 31 , 2815 – 2826.  

    50. Simoes , J. C. and Zagorodnov , V. S . 2001 . The record of anthropogenic pollution in snow and ice in Svalbard, Norway . Atmos. Environ . 35 , 402 – 413 .  

    51. Sueker , J. K. , Clow , D. W. , Ryan , J. N. and Jarret , R. D. 2001. Effect of basin physical characteristics on solute fluxes in nine Alpine/subalpine basins, Colorado, USA. Hydrol. Proc. 15, 2749 – 2769.  

    52. Sun , J. Y. , Qin , D. H. , Mayewski , P. A. , Dibb , J. E. , Whitlow , S. and co-authors 1998. Soluble species in aerosol and snow and their rela-tionship at Glacier 1, Tien Shan, China./. Geophys. Res. Lett.—Atmos. 103(1)21), 28,021 – 28,028.  

    53. Teinilä , K. , Hillamo , R. , Kerminen , V.-M. and Beine , H. J . 2003 . Aerosol chemistry during the NICE dark and light campaigns . Atmos. Environ . 37 , 563 – 575 .  

    54. Tockner , K. , Malard , F , Uehlinger , U. and Ward , J. V . 2002 . Nutrients and organic matter in a glacial river-floodplain system (Val Roseg, Switzerland) . Limnol. Oceanogr . 47 , 266 – 277 .  

    55. Tranter , M. , Brimblecombe , P. , Davies , T. D. , Vmcent , P. W. and Black-wood , I . 1986 . The composition of snowfall, snowpack and meltwater in the Scottish Highlands - Evidence for preferential elution . Atmos. Environ . 20 , 517 – 525 .  

    56. Tranter , M. , Davies , T. D. , Abrahams , P. W. , Blackwood , I. , Brimble-combe, P. and co-authors 1987. Spatial variability in the chemical compositions of snowcover in a small, remote, Scottish catchment. Atmos. Environ. 21, 853 – 862.  

    57. Tranter , M. , Tsiouris , S. , Davies , T. D. and Jones , H. G . 1992 . A labora-tory investigation of the leaching of solute from snowpack by rainfall . Hydrol. Proc . 6 , 169 – 178 .  

    58. Tsiouris , S. , Vincent , C. E. , Davies , T. D. and Brimblecombe , P . 1985 . The elution of ions through field and laboratory snowpacks . Ann. Glaciol . 7 , 196 – 201 .  

    59. Torseth , K. Berg , T. , Hanssen , J. E. and Mario , S. 1999. Overvaking av langtransportert forurenset luft og nedbor. Atmosfwrisk tilforsel , 1998. Kjeller, Norsk institutt for luftforskning, SFT Rapport nr 768/00, NILU OR 27/99 .  

    60. Wadham , J. L. and Nuttall , A. M . 2002 . Multiphase formation of su-perimposed ice during a mass-balance year at a maritime high-Arctic glacier . J. Glaciol . 48 , 545 – 551 .  

    61. Weller , R. , Traufetter , F , Fischer , H. , Oerter , H. , Piel , C. and co-authors 2004. Postdepositional losses of methane, nitrate and chloride at the European Project for Ice Coring in Antarctica deep-drilling site in Dronning Maud Land, Antarctica. Geophys. Res. 109, D07301 . d.o.i https://doi.org/10.1029/2003JD004189 .  

    62. White , A. E , Bullen , T. D. , Vivit , D. V. , Schulz , M. S. and Clow , D. W . 1999 . The role of disseminated calcite in the chemical weathering of granitoid rocks . Geochimica et Cosmochimica Acta 63 , 1939 – 1953 .  

    63. Williams , M. W. and Melack , J. M . 1991 . Precipitation chemistry and ionic loading to an alpine basin, Sierra Nevada . Water Resour. Res . 27 , 1563 – 1574 .  

    64. Williams , M. W. Tonnesson , K. A. , Melack , J. M. and Daqing , Y . 1992 . Sources and spatial variation of the chemical composition of snow in the Tien Shan, China . Ann. Glaciol . 6 , 25 – 32 .  

    65. Williams , M. W. , Brooks , P. D. , Mosier , A. and Tonnessen , K. A . 1996 . Mineral nitrogen transformations in and under seasonal snow in a high-elevation catchment in the Rocky Mountains, United States . Water Resour. Res . 32 , 3161 – 3171 .  

    66. Wolff , G. T . 1984 . On the nature of nitrate in coarse continental aerosols . Atmos. Environ . 18 , 977 – 981 .  

    67. Wu , P. M. and Okada , K. 1994. Nature of coarse nitrate particles in the atmosphere-a single particle approach. Atmos. Environ. 28, 2053 – 2060.  

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